We also use ZFS to store the website files and database, though this is a far simpler setup.  We have a single dataset, dtechwebsite, that stores all of the website files and another, mysql, that stores the database for the WordPress portions of the site.  These are located on ist-49 and backed up to occ-ist-8.  A listing of the datasets looks like this:

pool 6.80G 31.7G 19K none
pool/dtechwebsite 6.62G 31.7G 6.14G /var/www/html
pool/mysql 116M 31.7G 34.1M /var/lib/mysql